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Nitrogen
in tires is becoming a popular replacement for standard air.
Nitrogen is all around us... the air we breathe is 78% nitrogen,
21% oxygen and the rest is small amounts of other gasses.
When it comes to tire inflation, nitrogen has many advantages
over oxygen. With nitrogen tire inflation, improvements can
be noted in a vehicle's handling, fuel efficiency and tire
life through better tire pressure retention, improved fuel
economy and cooler running tire temperatures. Here at the
Get Nitrogen Institute our goal is to provide consumers, over-the-road
truckers, fleet managers and others information about the
benefits of using nitrogen in tires.
Fundamentally,
air, oxygen and nitrogen will all behave exactly the same,
in terms of just how much pressure will change for each 10
degrees of temperature change. However, temperature alone
is not the whole story. Ambient air contains moisture, which
nitrogen does not. If moisture is there, it contributes to
a greater change in pressure, simply because at lower temp,
water condenses to become a liquid. A liquid form of water
occupies very little volume and contributes only a negligible
pressure to the tire. But at higher temp, water becomes a
gas; water evaporates inside the tire as temperature rises.
With ambient air, which contains about 20.9% oxygen, the oxygen
permeates through the rubber of the tire, so some leaks out.
With nitrogen, containing only a little residual oxygen, pressure
changes due to oxygen loss are greatly reduced. So, on both
counts, the race car guys are correct; nitrogen is more predictable
- nitrogen is dry; it has no moisture to contribute extra
pressure changes with temperature. And nitrogen permeates
out much slower than oxygen, so pressure changes due to that
leakage are almost eliminated, compared with ambient air.
Lets
get a little deeper into the science. Keep in mind if the
air in your tire today changes about 1psi for every 10 degree
temperature change, a significant change in temperature will
create a significant change in your tire pressure. Here is
a set of Ideal Gas Law calculations, on the effects of a 10F
degree temperature change, on either truck or passenger tires,
filled initially at either 60F or at 90F. So, overall, about
.8 psi per 10 degrees is one study and 2.2psi for truck tires,
but the detail depends on the initial tire pressure and initial
temperature.
Calculate
pressure change expected for each 10F degrees temperature
change:
The final
pressure is calculated based on the Ideal Gas Law, where for
this discussion on P and T change, while n, R, and V are fixed
or constant.
P*V =
n*R*T This is the Ideal Gas Law equation.
P/T =
(n*R/V) by algebra, rearranging the formula for the Ideal
Gas Law.
then
Pinitial/Tinitial
= (n*R/V) = Pfinal/Tfinal since n, R, and V are all constant,
that is,
it assumes
no volume (V) change (i.e., no significant stretching of the
tire rubber);
the "n"
is how much gas is in a tire (the amount of gas is constant
for this discussion, covering a time frame very short compared
to the time it takes for gas to permeate through the tire
rubber)
the "R"
is the "ideal gas law constant" of proportionality,
so it does not change either;
then
Pfinal
= [Pinitial * (Tfinal/Tinitial)] by rearranging, we can calculate
Pfinal by multiplying Pinitial by the ratio of Tfinal to Tinitial
Note:
temperatures must be converted to Kelvin units (K), from Fahrenheit
units (F), for this calculation.

Any
questions about kits, parts, installations or services are
welcome. Contact Bishop by phone at 866-867-8324 or
e-mail bishop@bishopsales.com
and we will respond promptly. If you're in the neighborhood,
then drop by the shop at 1130 West 15th Street North Vancouver
BC and we will gladly give you a tour of our facilities, but
beware there may be a Monster and ferocious horsepower
beasts in our shop when you visit! We really love to share
the fun with other performance enthusiasts who want to take
their cars to the next level of performance, appearance and
handling!
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